The Journal of Organic Chemistry

Facile palladium-catalyzed decarboxylation reaction of allylic. beta.-keto esters

J Tsuji, M Nisar, I Shimizu

Index: Tsuji, Jiro; Nisar, Mohammad; Shimizu, Isao Journal of Organic Chemistry, 1985 , vol. 50, # 18 p. 3416 - 3417

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Citation Number: 94

Abstract

“Method A ester (1 mmol), Pd (OA& (0.025 mmol), PPh3 (0.05 mmol), HCO2HNEt8 in THF at room temperature (see, Experimental Section). Method B: ester (1 mmol), Pd (OA& (0.025 mmol), PPha (0.05 mmol), ammonium formate (2.0 mmol) in boiling dioxane.* All products were identified with authentic samples.