Functionalized 13-crown-4, 14-crown-4, 15-crown-4, and 16-crown-4 compounds: synthesis and lithium ion complexation

…, DA Babb, B Son, RA Bartsch

Index: Czech, Bronislaw P.; Babb, David A.; Son, Byungki; Bartsch, Richard A. Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4805 - 4810

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Citation Number: 63

Abstract

Seven novel (benzy1oxy) methyl-substituted crown ethers with four ring oxygens and 13-, 14- , 15, and 16-membered polyether rings are synthesized and their lithium and sodium cation- binding abilities are assessed by solvent extraction of the aqueous alkali metal picrates. Strongest lithium ion complexation is observed with [(benzyloxy) methyl]-l4-crown-4 compounds.

~10%

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