The selective C-mono-and C, C-dialkylation of thiophosphorylacetonitriles and reactivity of the products

NM Vinogradova, IL Odinets, OI Artyushin…

Index: Vinogradova, Natalya M.; Odinets, Irene L.; Artyushin, Oleg I.; Lyssenko, Konstantin A.; Petrovsky, Pavel V.; Mastryukova, Tatyana A. Phosphorus, Sulfur and Silicon and Related Elements, 1999 , vol. 144-146, p. 589 - 592

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Citation Number: 3

Abstract

The facile synthetic route to selective C-mono-and C, C-dialkylation of thiophosphorylacetonitriles by primary haloalkanes under phase transfer catalysis conditions has been developed. Using under the same conditions unsymmetric α, ω- dihaloalkanes results in different linear and cyclic products depending on the alkylene chain length. 3-Halopropylsubstituted thiophosphorylacetonitriles synthesized transform to ...