Mechanism of the diphenyldisulfone-catalyzed isomerization of alkenes. Origin of the chemoselectivity: experimental and quantum chemistry studies

…, A Varela-Álvarez, JA Sordo, P Vogel

Index: George, Adrian V.; Isaacs, Neil S. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1845 - 1848

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Citation Number: 18

Abstract

... Journal of the ... 2006, 128 (24), pp 7782–7795. DOI: 10.1021/ja0579210. Publication Date (Web): May 24, 2006. Copyright © 2006 American Chemical Society. ... in mechanism A and C of Scheme 4 but a two-step process involving first the addition of sulfonyl radical RSO 2 • onto the ...