Organic letters

Organocatalytic Dakin Oxidation by Nucleophilic Flavin Catalysts

S Chen, MS Hossain, FW Foss Jr

Index: Roy, Amrita; Reddy; Mohanta, Pramod K.; Ila; Junjappa Synthetic Communications, 1999 , vol. 29, # 21 p. 3781 - 3791

Full Text: HTML

Citation Number: 31

Abstract

... Volume: Page: ... To broaden the synthetic capability of flavin catalysts to useful nucleophilic oxidations, the Dakin oxidation of electron-rich benzaldehydes ... Linear agreements occurred between the individual and summed(58) σ i values and log(k R /k H ) yielding ...

 Related Synthetic Route
naphthal Structure

66-77-3

naphthal

~52%

1-Naphthalenol Structure

90-15-3

1-Naphthalenol

1'-Acetonaphthone Structure

941-98-0

1'-Acetonaphthone

~39%

1-Naphthalenol Structure

90-15-3

1-Naphthalenol

2-Methylbenzyl Alcohol Structure

89-95-2

2-Methylbenzyl ...

~77%

1,2-Benzenediol Structure

120-80-9

1,2-Benzenediol

Ortho-Hydroxyacetophenone Structure

118-93-4

Ortho-Hydroxyac...

~92%

1,2-Benzenediol Structure

120-80-9

1,2-Benzenediol

VHR BO2U1 Structure

28752-82-1

VHR BO2U1

~91%

2-Allyloxyphenol Structure

1126-20-1

2-Allyloxyphenol

4-Hydroxyacetophenone Structure

99-93-4

4-Hydroxyacetop...

~83%

Hydroquinone Structure

123-31-9

Hydroquinone

4-Methoxybenzaldehyde Structure

123-11-5

4-Methoxybenzal...

~96%

Mequinol Structure

150-76-5

Mequinol

Acetanisole Structure

100-06-1

Acetanisole

~73%

Mequinol Structure

150-76-5

Mequinol

2,3-Dimethoxybenzaldehyde Structure

86-51-1

2,3-Dimethoxybe...

~77%

dimethoxyphenol Structure

5150-42-5

dimethoxyphenol

Acetophenone Structure

98-86-2

Acetophenone

~15%

benzoic acid Structure

65-85-0

benzoic acid

Phenol Structure

108-95-2

Phenol


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