Synthesis of 2, 3-acetylenic amines by aminomethylation of acetylenes with geminal diamines

MG Shaibakova, IG Titova, GA Makhmudiyarov…

Index: Shaibakova; Titova; Makhmudiyarov; Ibragimov; Dzhemilev Russian Journal of Organic Chemistry, 2010 , vol. 46, # 1 p. 43 - 48

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Citation Number: 8

Abstract

Abstract A general and effective procedure has been developed for the synthesis of symmetrical and unsym-metrical 2, 3-acetylenic amines by aminomethylation of terminal mono-and diacetylenes with geminal diamines in the presence of transition metal salts and complexes.

~94%

~10%

~86%

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