Journal of heterocyclic chemistry

1??Methyl??3??phenyl??3??thiocyanato??1H, 3H??quinoline??2, 4??dione: A novel thiocyanating agent

A Klásek, V Mrkvička

Index: Klasek, Antonin; Mrkvicka, Vladimir Journal of Heterocyclic Chemistry, 2003 , vol. 40, # 5 p. 747 - 752

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Citation Number: 13

Abstract

Abstract Under mild reaction conditions, the thiocyanato group is selectively transferred from 1-methyl-3-phenyl-3-thiocyanato-1H, 3H-quinoline-2, 4-dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S-cyanothiohydroxylamines, anilines afford p-thiocyanatoanilines, Wittig reagent is thiocyanated in α-position, and thiols are oxidized to disulfides.