Mechanistic studies on palladium-catalyzed double carbonylation of aryl iodides affording α-keto esters

H Yamashita, T Sakakura, TA Kobayashi…

Index: Yamashita; Sakakura; Kobayashi; Tanaka Journal of molecular catalysis, 1988 , vol. 48, # 1 p. 69 - 79

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Citation Number: 12

Abstract

Abstract In relation to the mechanism of palladium-catalyzed carbonylation of aryl iodides to give α-keto esters, the carbonylation reactivity of some palladium complexes such as RPdIL 2 (I: R= C 6 H 5, L= P (C 6 H 5) 3; II: R= C 6 H 5 CO, L= P (C 6 H 5) 3) and C 6 H 5 COPd [ ...