Russian Journal of Applied Chemistry

Effect of structural factors and solvent nature in bromination of anilines

BT Bagmanov

Index: Bagmanov Russian Journal of Applied Chemistry, 2009 , vol. 82, # 9 p. 1570 - 1576

Full Text: HTML

Citation Number: 10

Abstract

Abstract Reaction of electrophilic bromination of aniline containing various ortho, meta, and para substituents in the aromatic ring was studied. The optimal conditions for synthesis of mono-, di-, tri-, and tetrabromo derivatives of aniline and brominated analog of Aniline Black were found.

 Related Synthetic Route
ZR BE DVQ Structure

6311-37-1

ZR BE DVQ

~90%

4-Amino-3,5-dibromobenzoic acid Structure

4123-72-2

4-Amino-3,5-dib...

2-Bromo-4-nitroaniline Structure

13296-94-1

2-Bromo-4-nitro...

~88%

2,6-Dibromo-4-nitroaniline Structure

827-94-1

2,6-Dibromo-4-n...

2-Bromo-p-toluidine Structure

583-68-6

2-Bromo-p-toluidine

~89%

2,6-Dibromo-p-toluidine Structure

6968-24-7

2,6-Dibromo-p-t...

3-anisidine Structure

536-90-3

3-anisidine

~88%

2,4-dibromo-5-methoxyaniline Structure

35736-52-8

2,4-dibromo-5-m...

4-Bromo-2-chloroaniline Structure

38762-41-3

4-Bromo-2-chlor...

~96%

2-chloro-4,6-dibromoaniline Structure

874-18-0

2-chloro-4,6-di...

4-Bromo-2-nitroaniline Structure

875-51-4

4-Bromo-2-nitro...

~97%

2,4-Dibromo-6-nitroaniline Structure

827-23-6

2,4-Dibromo-6-n...

4-Bromoaniline Structure

106-40-1

4-Bromoaniline

~10%

2,4-Dibromoaniline Structure

615-57-6

2,4-Dibromoaniline

4-Bromo-o-anisidine Structure

59557-91-4

4-Bromo-o-anisidine

~92%

2,4-Dibromo-6-methoxyaniline Structure

88149-47-7

2,4-Dibromo-6-m...

Anthranilic acid Structure

118-92-3

Anthranilic acid

~98%

2-Amino-5-bromobenzoic acid Structure

5794-88-7

2-Amino-5-bromo...

4-Aminobenzoic acid Structure

150-13-0

4-Aminobenzoic acid

~10%

ZR BE DVQ Structure

6311-37-1

ZR BE DVQ

2-Anisidine Structure

90-04-0

2-Anisidine

~99%

4-Bromo-o-anisidine Structure

59557-91-4

4-Bromo-o-anisidine


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