Synthesis of 1, 2, 4-Trimethoxybenzene and Its Selective Functionalization at C-3 by Directed Metalation

…, GBA Slana, JN Cardoso, Q Wang…

Index: Alves, Ana P. L.; Junior, Jose Augusto B. C.; Slana, Glaucia B. A.; Cardoso, Jari N.; Wang, Qiang; Lopes, Rosangela S. C.; Lopes, Claudio C. Synthetic Communications, 2009 , vol. 39, # 20 p. 3693 - 3709

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Abstract

Indol (1) is one of the N-heterocyclic compounds most widespread among floral scents in nature, and 1,2,4-trimethoxybenzene can be found in the volatiles of Cucurbita, Cymbidium, Hyacinthus, Pyrola, and Syringa species. [ 1 1. Knudsen , JT ; Tollsten , L. ; Bergstrom , LG Floral scents a checklist of volatile compounds isolated by head-space techniques . Phytochemistry 1993 , 33 , 253 – 280 . [CrossRef], [Web of Science ®], [CSA] View all references ] The ...