Ein einfaches Verfahren zur Herstellung von organozinnaziden. Synthese and struktur der sterisch gehinderten Stannylazide t Bu 3 SnN 3 und t Bu 2 Sn (N 3) 2

D Hänssgen, M Jansen, C Leben, T Oster

Index: Haenssgen, Dieter; Jansen, Martin; Leben, Christiane; Oster, Thomas Journal of Organometallic Chemistry, 1995 , vol. 494, # 12 p. 223 - 228

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Citation Number: 9

Abstract

Sterically crowded stannyl azides tBunSn (N3) 4-n (IIa, b) have been prepared for the first time by the reactions of stannylamines tBunSn (NHR) 4-n (Ia, b) with Me3SiN3 (a: n= 3, R= H; b: n= 2, R= tBu). The novel compounds were characterized by NMR (1H, 13C) and mass spectroscopy and their molecular structure determined by X-ray crystallography (IIa: space group P21/m, Z= 2; IIb: space group P21/n, Z= 4).