Azidotrimethylsilane

Modify Date: 2024-01-02 20:27:51

Azidotrimethylsilane Structure
Azidotrimethylsilane structure
Common Name Azidotrimethylsilane
CAS Number 4648-54-8 Molecular Weight 115.209
Density 0.876 g/mL at 20 °C(lit.) Boiling Point 92-95 °C(lit.)
Molecular Formula C3H9N3Si Melting Point -95°C
MSDS Chinese USA Flash Point 74 °F
Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger

 Names

Name Azidotrimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.876 g/mL at 20 °C(lit.)
Boiling Point 92-95 °C(lit.)
Melting Point -95°C
Molecular Formula C3H9N3Si
Molecular Weight 115.209
Flash Point 74 °F
Exact Mass 115.056572
PSA 49.75000
LogP 0.65
Index of Refraction n20/D 1.415(lit.)
Storage condition Refrigerator
Water Solubility decomposes

 Safety Information

Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger
Hazard Statements H225-H301 + H311 + H331
Precautionary Statements P210-P261-P280-P301 + P310-P311
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;T:Toxic;N:Dangerousfortheenvironment;
Risk Phrases R11;R23/24/25;R29;R50/53
Safety Phrases S16-S36/37/39-S45-S8-S57-S36/37-S29
RIDADR UN 1992 3/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 3
HS Code 29310095

 Synthetic Route

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles8

More Articles
Preparation of the first manganese(III) and manganese(IV) azides.

Angew. Chem. Int. Ed. Engl. 53(31) , 8200-5, (2014)

Fluoride-azide exchange reactions of Me3SiN3 with MnF2 and MnF3 in acetonitrile resulted in the isolation of Mn(N3)2 and Mn(N3)3 ⋅CH3CN, respectively. While Mn(N3)2 forms [PPh4]2[Mn(N3)4] and (bipy)2M...

The Vanadium(V) Oxoazides [VO(N3)3], [(bipy)VO(N3)3], and [VO(N3)5](2-).

Angew. Chem. Int. Ed. Engl. 54 , 9101-5, (2015)

Vanadium(V) oxoazide [VO(N3)3] was prepared through a fluoride-azide exchange reaction between [VOF3] and Me3SiN3 in acetonitrile solution. When the highly impact- and friction-sensitive compound [VO(...

J. Am. Chem. Soc. 115 , 9347, (1993)

 Synonyms

Azido(trimethyl)silane
Azidotrimethylsilane
TriMethylsilylazide
Silane, azidotrimethyl-
MFCD00001986
Trimethylsilyl azide
EINECS 225-078-5
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