Exchanges of Halogen and Hydrogen Between Organic Halides and Isoparaffins in the Presence of Aluminum Halides

…, FE Condon, A Schneider

Index: Bartlett; Condon; Schneider Journal of the American Chemical Society, 1944 , vol. 66, p. 1531,1538

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Citation Number: 111

Abstract

mixture of the dimethyl ether XVIII (4.78 g.), hydrobromic acid (48 cc., 48%), and acetic acid (66 cc.) was rehxed for two and one-half hours. The dark solution was poured into water, and the solid was removed and crystallized from benzene-petroleum ether (bp 30- 60;)(Norit). The product (2.74 g., 63%) melted at 139-141. A sample, recrystallized several times, melted at 142-143'. Anal. Calcd. for CP~ H~ O~: C, 82.86; H, 6.62.