Formation of. alpha.,. beta.-unsaturated ketones from the gas-phase pyrolysis of. alpha.-substituted propargyl esters

WS Trahanovsky, SL Emeis

Index: Trahanovsky,W.S.; Emeis,S.L. Journal of the American Chemical Society, 1975 , vol. 97, p. 3773 - 3777

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Citation Number: 11

Abstract

Abstract: Products from the low pressure ( Torr) gas-phase pyrolysis of the following a- substituted propargyl esters were determined: 1-phenylpropargyl hexanoate (1); 1- methylpropargyl benzoate (2); 1, I-dimethylpropargyl benzoate (3); 1, I-dimethylpropargyl hexanoate (4); 1-propylpropargyl benzoate (5); I-isopropylpropargyl benzoate (8); I- ethynylcyclohexyl benzoate (6); I-ethynylcyclopentyl benzoate (7). With the exception of 7, ...

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