Aryl halides as convenient precursors of electrogenerated bases. Efficient syntheses of β-oxo nitriles or esters by coupling active-hydrogen groups with esters

R Barhdadi, J Gal, M Heintz, M Troupel

Index: Barhdadi, Rachid; Gal, Jacques; Heintz, Monique; Troupel, Michel Journal of the Chemical Society, Chemical Communications, 1992 , # 1 p. 50 - 51

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Citation Number: 8

Abstract

In an undivided cell fitted with a sacrifical anode and a nickel cathode on which cadmium had been deposited, the electroreduction of aromatic halides affords a strong base which allows the effective synthesis of β-oxo nitriles or β-oxo esters from the coupling of active- hydrogen compounds with esters.

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