N-DICHLOROACETYL DERIVATIVES OF SERINE AND THREONINE AND OF THEIR ESTERS AND SODIUM SALTS

I Levi, AE Koller, G Laflamme…

Index: Levi,I. et al. Canadian Journal of Chemistry, 1960 , vol. 38, p. 1135 - 1140

Full Text: HTML

Citation Number: 3

Abstract

The N-dichloroacetyl derivatives of dl-serine and dl-threonine were prepared by the Schotten-Baumann reaction from the amino acids and dichloroacetyl chloride. Negative ninhydrin tests coupled with elementary analyses indicated that only the amino group was acylated. The ester derivatives of these compounds were prepared either by esterification of the N-dichloroacetyl-dl-amino acid with diazomethane or by the reaction of the amino acid ...