Liebigs Annalen der Chemie

Orthoamide, XLVI. Beiträge zur Chemie von Bis (dialkylamino) malononitrilen

W Kantlehner, U Greiner

Index: Kantlehner, Willi; Greiner, Ulrich Liebigs Annalen der Chemie, 1990 , # 10 p. 965 - 973

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Citation Number: 11

Abstract

The reaction of chloroformamidinium chlorides 2 with sodium cyanide in the two-phase system etherlwater affords bis (di-alky1amino) malononitriles 3 with good yields. From 3a and morpholine or aniline the guanidines 5 and 6 can be obtained, respectively. Alcohol- free sodium ethoxide transforms 3a into the urea acetal lob, whereas in the reaction of 3a with alkoxides in alcohol ortho carbamic esters lla, b are produced. The malonic esters ...