Journal of organometallic chemistry

Rhodium complex catalyzed hydroformylation reactions of linear and cyclic mono-and diolefins

AM Trzeciak, JJ Ziółkowski

Index: Trzeciak, Anna M.; Ziolkowski, Jozef J. Journal of Organometallic Chemistry, 1994 , vol. 479, # 1-2 p. 213 - 216

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Citation Number: 17

Abstract

Abstract The hydroformylation reactions of cyclopentene, cyclohexene, 4-vinylcyclohexene, cycloheptene and cyclooctene, catalyzed with a Rh (acac){P (OPh) 3} 2/P (OPh) 3 (I) system at 80 C and 10 atm (CO+ H 2), have been studied. Only cyclopentene and 4-vinylcy- clohexene undergo hydroformylation at 1 atm and 40 C. The hydroformylation of some cyclic dienes;(1, 3-and 1, 4-cyclohexadienes, 1, 3-and 1, 5-cyclooctadienes and 1, 3- ...