Carbohydrate research

Chloramine-T-mediated chemoselective hydrolysis of thioglycosides into glycosyl hemiacetals under neutral conditions

AK Misra, G Agnihotri

Index: Misra, Anup Kumar; Agnihotri, Geetanjali Carbohydrate Research, 2004 , vol. 339, # 4 p. 885 - 890

Full Text: HTML

Citation Number: 26

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... A metal-free, mild, efficient and chemoselective hydrolysis of several thioalkylglycosides (1) into their corresponding 1-hydroxy sugars (2) using sodium N-chloro-p-toluenesulfonamide trihydrate (chloramine-T) without affecting other functional groups is reported.

 Related Synthetic Route
Phenyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside Structure

167612-35-3

Phenyl 2,3,4-tr...

~%

2,3,4-tri-o-benzyl-l-fucopyranose Structure

33639-75-7

2,3,4-tri-o-ben...

N/A Structure

127875-50-7

N/A

b-D-Glucopyranoside, phenylmethyl1-thio-, 2,3,4,6-tetraacetate Structure

6612-63-1

b-D-Glucopyrano...

~84%

2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE Structure

3947-62-4

2,3,4,6-TETRA-O...

2,3,4,6-tetra-O-acetyl-1-deoxy-1-(p-nitrobenzylthio)-β-D-glucopyranose Structure

35785-63-8

2,3,4,6-tetra-O...

~80%

2,3,4,6-TETRA-O-ACETYL-BETA-D-GLUCOSE Structure

3947-62-4

2,3,4,6-TETRA-O...


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved