Journal of organometallic chemistry

Cycloauration of substituted 2-phenoxypyridine derivatives and X-ray crystal structure of gold, dichloro [2-[[5-[(cyclopentylamino) carbonyl]-2-pyridinyl-κN] oxy] phenyl- …

Y Zhu, BR Cameron, RT Skerlj

Index: Zhu, Yongbao; Cameron, Beth R.; Skerlj, Renato T. Journal of Organometallic Chemistry, 2003 , vol. 677, # 1-2 p. 57 - 72

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Abstract

Direct cycloauration of 2-phenoxypyridines with different substituents at the 5-position of the pyridine ring was carried out in an CH3CN/H2O medium, leading to isolation of cycloaurated compounds AuCl2 (L)(HL= substituted 2-phenoxypyridine ligand) with alkyl, substituted alkyl, phenyl, halo, ester and amido groups. The preparation of cycloaurated compounds involves the formation of an intermediate AuCl3 (HL) via coordination reaction between ...