Tetrahedron letters

Catalyst dependent mechanistic paths in the reactions of ethyl diazoacetate with β-keto esters

AC Lottes, JA Landgrebe, K Larsen

Index: Lottes, Andrew C.; Landgrebe, John A.; Larsen, Kristin Tetrahedron Letters, 1989 , vol. 30, # 31 p. 4093 - 4096

Full Text: HTML

Citation Number: 9

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The catalyzed decomposition of ethyl diazoacetate in the presence of β-keto esters produces regioisomeric enol ethers and the diester from formal carbenoid insertion into the α-CH bond. The product distribution is very catalyst dependent. ... Equilibration does occur in ...