Synthesis and modification of spacered glycosides of N-acetylglucosamine

AE Zemlyakov, VO Kur'yanov, EA Sidorova…

Index: Zemlyakov; Kur'yanov; Sidorova; Chupakina; Chirva Chemistry of Natural Compounds, 1997 , vol. 33, # 5 p. 563 - 567

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Citation Number: 2

Abstract

Abstract From glucosaminyl chloride peracetate, in the presence of HgI 2, we have obtained β-p-nitrobenzyl-, β-ω-chloro-and β-ω-azido-spacered glycosides of N-acetylglucosamine (NAG) with spacers of different lengths and chemical natures. The corresponding amino derivatives have been synthesized from them. The possibility has been shown of modifying the ω-chloro-and ω-azido-spacered glycosides of NAG.