1, 3-Adamantane-3, 13-porphyrin-6, 6-cyclophane: crystal structure of the free base and steric effects on ligation of the iron (II) complex

TG Traylor, N Koga, LA Deardurff…

Index: Traylor, T. G.; Koga, N.; Deardruff, L. A.; Sweptson, Paul N.; Ibers, James A. Journal of the American Chemical Society, 1984 , vol. 106, # 18 p. 5132 - 5143

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Citation Number: 43

Abstract

Abstract: The coupling of 1, 3-adamantanediacetyl chloride to 8, 18-bis (2- carbobenzoxyethyl)-3, 13-bis (o-aminopropyl)-2, 7, 12, 17-tetramethylporphyrin affords 1, 3- adamantane-3, 13-porphyrin-6, 6-cyclophane. The material crystallizes as the bis (dich1oromethane) solvate, C64H72N606. 2CH2C12, in space group C,'-PT of the triclinic system with two formula units in a cell of dimensions a= 15.858 (28) A, b= 17.779 (32) A, c ...