The Journal of Organic Chemistry

Vinyl cations. 19. Preparation and solvolysis of (1-bromo-1-arylmethylene) cyclopropanes. Effect of p-aryl substituents on the generation of stabilized vinyl cations

J Salaun, M Hanack

Index: Salaun,J.; Hanack,M. Journal of Organic Chemistry, 1975 , vol. 40, # 13 p. 1994 - 1998

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Citation Number: 20

Abstract

Vinyl cation intermediates are now readily available in solvolysis reactions either through heterolysis of vinyl substrates or triple bond participations. 2 Although vinyl cations are generally less stable than the corresponding saturated carbenium ions, 3 recent studies have given evidence for their formation.