Kinetic study of double-bond migration in allyloxy polyether alkoxides

EC Steiner, RO Trucks

Index: Steiner,E.C.; Trucks,R.O. Journal of the American Chemical Society, 1968 , vol. 90, # 3 p. 720 - 726

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Citation Number: 4

Abstract

Abstract: The rates of rearrangement of CH2= CHCH2 (0C3H&O-M+ to cis-CH3CH= CH (OC3H&0-M+ have been studied kinetically at 30" in tetrahydrofuran solution. The Cs+ compounds react about 60 times as fast as the K+ compounds; the Na+ compounds do not rearrange under the conditions used, The rates depend on the value of n, being maximum when n= 3 in the K+ series and when n= 3 or 4 in the Csf series, Chelation of cation by the ...