Substituted tertiary phosphine Ru (II) organometallics: Catalytic utility on the hydrolysis of etofibrate in pharmaceuticals

PM Reddy, K Shanker, R Rohini, M Sarangapani…

Index: Reddy, P. Muralidhar; Shanker, Kanne; Rohini, Rondla; Sarangapani; Ravinder, Vadde Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2008 , vol. 70, # 5 p. 1231 - 1237

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Citation Number: 11

Abstract

Some new organometallics of ruthenium (II) of the type [RuCl2 (COD)(CO) L](1a–f) and [RuCl2 (COD) L2](2a–f)(where L is substituted tertiary phosphines), have been synthesized by using precursors [RuCl2 (COD)(CO)(CH3CN)](1) and [RuCl2 (COD)(CH3CN) 2](2) with the substituted tertiary phosphine ligands in 1: 1 and 1: 2 molar ratio. The organometallics (2a–f) have been further reacted with carbonmonoxide to produce compounds of the type [ ...