Conformational analysis of cycloartenol, 24-methylenecycloartanol and their derivatives

K Yoshida, Y Hirose, Y Imai, T Kondo

Index: Yoshida, Kumi; Hirose, Yoshihiko; Imai, Yutaka; Kondo, Tadao Agricultural and Biological Chemistry, 1989 , vol. 53, # 7 p. 1901 - 1912

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Citation Number: 27

Abstract

A conformational analysis of cycloartenol, 24-methylenecycloartanol and their derivatives was carried out in the solution and the solid state by an NMR study and X-ray crystallographic analysis, respectively. Complete assignments of the 1HNMR spectra of these compounds were made in order to elucidate the conformation involving the ring system and side chain. Rings A to C had a chair-halfchair-boat conformation, and the side ...