Six-co-ordinated vanadium-(IV) and-(V) complexes of benzimidazole and pyridyl containing ligands

…, AD Keramidas, SS Amin, OP Anderson…

Index: Crans, Debbie C.; Keramidas, Anastasios D.; Amin, Sean S.; Anderson, Oren P.; Miller, Susie M. Journal of the Chemical Society - Dalton Transactions, 1997 , # 16 p. 2799 - 2812

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Citation Number: 43

Abstract

A new series of vanadium-(IV) and-(V) complexes with ligands containing functionalities including hydroxyethyl, carboxylate, amine, pyridyl and benzimidazole have been prepared. The crystal structures of three complexes have been determined. All the vanadium atoms are six-co-ordinate even though previous complexes of the diethanolamine type have contained five-co-ordinate vanadium. The V–N (amine) bonds of the benzimidazole ...