Tetrahedron

N, N-dihalophosphoramides—I: Synthesis of diethyl N, N-dichlorophosphoroamidate (DCPA) and some of its structural analogues

A Zwierzak, A Koziara

Index: Zwierzak,A.; Koziara,A. Tetrahedron, 1970 , vol. 26, p. 3521 - 3525

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Citation Number: 11

Abstract

Diethyl N, N-dichlorophosphoroamidate (DCPA), a stable, easily distillable, but very reactive pseudo-halogen containing phosphorus has been prepared in excellent yield by direct chlorination of diethyl phosphoroamidate in buffered aqueous acid solution. The reaction was found to be of general use for the preparation of some structural analogues of DCPA.