Green synthesis and self-association of 2, 4-diamino-1, 3, 5-triazine derivatives

…, M del Carmen Mateo, A Sánchez-Migallón…

Index: Diaz-Ortiz, Angel; Elguero, Jose; Foces-Foces, Concepcion; De La Hoz, Antonio; Moreno, Andres; Del Carmen Mateo, Maria; Sanchez-Migallon, Ana; Valiente, Gema New Journal of Chemistry, 2004 , vol. 28, # 8 p. 952 - 958

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Citation Number: 32

Abstract

2, 4-Diamino-1, 3, 5-triazines have been prepared by reaction of dicyandiamide with nitriles under microwave irradiation, a method that can be considered as a green procedure due to the reduction in the use of solvents during synthesis and purification, the short reaction time and the simplicity of the procedure. The structures have been confirmed in solution by NMR spectroscopy. Variable temperature experiments have been used to calculate the free ...