Tetrahedron

Organomanganese (II) reagents XV. Conjugate addition of organomanganese reagents to alkylidenemalonic esters and related compounds

G Cahiez, M Alami

Index: Cahiez, Gerard; Alami, Mouad Tetrahedron, 1989 , vol. 45, # 13 p. 4163 - 4176

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Citation Number: 86

Abstract

Lately, we have reported that organomanganese reagents react with cyclohexenone to give the 1,4 addition or the j3-reductive dimerixation product& ... R,M ti * THF a) Preparedjiom RMgX ... Unfortunately, the synthetic interest of these reactions is quite limited since, with most conjugated enones, they generally proceed in very poor yields (< 30 % ). Nevertheless, the study reported hereafter demonstrates that the ability of organomanganese reagents to add to a, ...