Oxidative and Enantioselective Cross??Coupling of Aldehydes and Nitromethane Catalyzed by Diphenylprolinol Silyl Ether

Y Hayashi, T Itoh, H Ishikawa

Index: Hayashi, Yujiro; Itoh, Takahiko; Ishikawa, Hayato Angewandte Chemie - International Edition, 2011 , vol. 50, # 17 p. 3920 - 3924

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Citation Number: 85

Abstract

Activation of the CÀH bond and transformation of this bond into a new CÀC bond is one of the fundamental transformations in organic chemistry.[1, 2] Recently, great progress has been achieved in the field of the activation of unreactive CÀH bonds, in which organometallic reagents play a central role. Moreover, it is one of the great synthetic challenges not only to transform the unreactive CÀH bond into a new CÀC bond but also ...