Journal of organometallic chemistry

Conversion of hydrosilanes to alkoxysilanes catalyzed by Cp 2 TiCl 2/n BuLi

TC Bedard, JY Corey

Index: Bedard, Thomas C.; Corey, Joyce Y. Journal of Organometallic Chemistry, 1992 , vol. 428, # 3 p. 315 - 333

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Citation Number: 67

Abstract

Abstract The combination of Cp 2 TiCl 2 and n BuLi provides an effective catalyst for alcoholysis of the model silanes n-HexSiH 3, PhMeSiH 2, Ph 2 SiH 2 and PhMe 2 SiH by ethanol, isopropanol, t-butyl alcohol and phenol. Increasing the steric bulk of the substituents on either the alcohol or the silane generally requires longer reaction periods and/or increasing temperature. All SiH bonds are converted to SiOEt groups by ethanol ...