Rational Design of a Palladium??Catalyzed Csp–Csp Cross??Coupling Reaction Inspired by Kinetic Studies

Y Weng, B Cheng, C He, A Lei

Index: Weng, Yue; Cheng, Ben; He, Chuan; Lei, Aiwen Angewandte Chemie - International Edition, 2012 , vol. 51, # 38 p. 9547 - 9551

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Citation Number: 35

Abstract

Owing to the unique chemical and physical properties of diynes, along with their wide applications in pharmaceuticals and materials chemistry, these compounds have attracted the attention of scientists for decades.[1] However, the synthesis of diynes still remains a great challenge. Compared with the intensively developed synthetic methods for biaryl and arylalkynes (Csp2–Csp2 and Csp2–Csp couplings), the methods for Csp–Csp coupling ...