Dehydrodimerization of ketones, carboxylic acids, amides, esters, alcohols, and amines, via mercury-photosensitization

CG Boojamra, RH Crabtree, RR Ferguson…

Index: Boojamra, Constantine G.; Crabtree, Robert H.; Ferguson, Richard R.; Muedas, Cesar A. Tetrahedron Letters, 1989 , vol. 30, # 41 p. 5583 - 5586

Full Text: HTML

Citation Number: 8

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Selective dehydrodimerization of the title compounds can be carried out on a preparative scale at 1 atm. and at 25°–110°C in a simple apparatus by Hg-photosensitized reaction under H 2 . ... All possible stereoisomers are formed, eg, D,L and meso mixtures for each of 1, 2, 6, ...

Detail

Detail

Hydrogen atoms as convenient synthetic reagents: mercury-pho...

[Muedas, Cesar A.; Ferguson, Richard R.; Brown, Stephen H.; Crabtree, Robert H. Journal of the American Chemical Society, 1991 , vol. 113, # 6 p. 2233 - 2242]

Silyl Ketene Acetal Chemistry: Steric Limitations in Lewis A...

[Wenke, G.; Jacobsen, E. N.; Totten, G. E.; Karydas, A. C.; Rhodes, Y. E. Synthetic Communications, 1983 , vol. 13, # 6 p. 449 - 458]

Photochemical reactions of arenecarboxylic acid esters with ...

[Cantrell, Thomas S.; Allen, Andrew C. Journal of Organic Chemistry, 1989 , vol. 54, # 1 p. 135 - 139]

Entropy control of the cross-reaction between carbon-centere...

[Sobek; Martschke; Fischer Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2849 - 2857]