The Journal of organic chemistry

A large accelerating effect of tri (tert-butyl) phosphine in the rhodium-catalyzed addition of arylboronic acids to aldehydes

M Ueda, N Miyaura

Index: Ueda, Masato; Miyaura, Norio Journal of Organic Chemistry, 2000 , vol. 65, # 14 p. 4450 - 4452

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Citation Number: 214

Abstract

The addition of a metal-carbon bond to the carbonheteroatom double bond is a very popular reaction in main group metal reagents of lithium and magnesium, but less attention has been paid to the corresponding reaction of transition-metal compounds. 1 However, the metal-catalyzed addition reactions are of interest due to their potential application to asymmetric synthesis. We previously demonstrated the efficiency of transmetalation from ...

~81%

~65%

~95%

~10%

~91%

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