Tetrahedron Letters

Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation

…, A Yoshimura, Y Wei, VN Nemykin, VV Zhdankin

Index: Zhu, Chenjie; Yoshimura, Akira; Wei, Yunyang; Nemykin, Victor N.; Zhdankin, Viktor V. Tetrahedron Letters, 2012 , vol. 53, # 12 p. 1438 - 1444

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Citation Number: 29

Abstract

Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2, 2, 6, 6- tetramethylpiperidin-1-yl) oxyl (TEMPO) and iodoarene moieties were developed and used for environmentally benign catalytic oxidation of alcohols. The reactions using peracetic acid as a green and practical co-oxidant afforded the corresponding carbonyl compounds in high yields under mild conditions and convenient work-up. Furthermore, these ionic liquid ...