Role of through space 2p-3d overlap in the alkylation of phosphines

WE McEwen, AB Janes, JW Knapczyk…

Index: Journal of the American Chemical Society, , vol. 100, p. 7304 - 7311

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Citation Number: 48

Abstract

... a large degree of positive charge is present on the phosphorus atom, and the phosphorus-halogen bond formation process is very near c0mp1etion.l~ Consequently, if the theory postulated by us is correct ... 7308 Journal of the American Chemical Society / 100:23 / November ...