Studies on the synthesis of heterocyclic compounds. XVI. Cleavage of 1, 3??benzodioxoles and??benzoxathioles by sodium iodide??acyl chloride

…, A Maccioni, AM Maccioni, G Podda

Index: Corda, Luciana; Fadda, Anna Maria; Maccioni, Antonio; Maccioni, Anna Maria; Podda, Gianni Journal of Heterocyclic Chemistry, 1988 , vol. 25, p. 311 - 314

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Citation Number: 7

Abstract

Abstract The cleavage reaction of ethereal and thioethereal bonds with sodium iodide and acyl chloride has been studied. In all the 1, 3-benzodioxoles and-benzoxathioles studied, the opening of the heterocyclic ring with formation of 1, 2-diacetoxybenzene or 2- hydroxythiophenol diacetic ester and gem-diiodoalkanes and iodoalkenes has been observed. The structure of newly prepared compounds has been determined by analytical ...