e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Chemistry of allene sulphoxides: novel transformations of acetylenic alcohols

I Cutting, PJ Parsons

Index: Cutting, Ian; Parsons, Philip J. Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210

Full Text: HTML

Citation Number: 0

Abstract

... Commun., 1983, 1209-1210. Chemistry of allene sulphoxides: novel transformations of acetylenic alcohols. (Note: The full text of this document is currently only available in the PDF Version ). Ian Cutting and Philip J. Parsons. The preparation and reactions of allenes derived from 1-phenylthio substituted acetylenic alcohols are described; this chemistry offers new routes to allenyl sulphides, acyl anion equivalents, and substituted unsaturated aldehydes.

cyclohexylidene-oxo-phenyl-(2-phenylsulfanylethenyl)-λ6-sulfane Structure

cyclohexylidene...

~51%

2-cyclohexylideneethenylsulfanylbenzene Structure

2-cyclohexylide...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

2-cyclohexylideneethenylsulfanylbenzene Structure

2-cyclohexylide...

1-Ethynyl-1-cyclohexanol Structure

1-Ethynyl-1-cyc...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~46%

cyclohexylidene-oxo-phenyl-(2-phenylsulfanylethenyl)-λ6-sulfane Structure

cyclohexylidene...

2-methyl-3,4-bis(phenylsulfanyl)but-3-en-2-ol Structure

2-methyl-3,4-bi...

~47%

3-methyl-2-phenylsulfanylbut-2-enal Structure

3-methyl-2-phen...

Sodium benzenethiolate Structure

Sodium benzenet...

~%

3-methyl-2-phenylsulfanylbut-2-enal Structure

3-methyl-2-phen...

3-Methyl butynol Structure

3-Methyl butynol

~%

3-methyl-2-phenylsulfanylbut-2-enal Structure

3-methyl-2-phen...

(3,7-dimethyl-1-(phenylsulfinyl)octa-1,2,6-trien-1-yl)(phenyl)sulfane Structure

(3,7-dimethyl-1...

~61%

3,7-dimethylocta-1,2,6-trienylsulfanylbenzene Structure

3,7-dimethyloct...

3,7-dimethyloct-6-en-1-yn-3-ol Structure

3,7-dimethyloct...

~%

3,7-dimethylocta-1,2,6-trienylsulfanylbenzene Structure

3,7-dimethyloct...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

3,7-dimethylocta-1,2,6-trienylsulfanylbenzene Structure

3,7-dimethyloct...

Sodium ethoxide Structure

Sodium ethoxide

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

~73%

(2-ethoxy-3-methylbut-1-enyl)sulfanylbenzene Structure

(2-ethoxy-3-met...

3-Methyl butynol Structure

3-Methyl butynol

~%

(2-ethoxy-3-methylbut-1-enyl)sulfanylbenzene Structure

(2-ethoxy-3-met...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

(2-ethoxy-3-methylbut-1-enyl)sulfanylbenzene Structure

(2-ethoxy-3-met...

1-Ethynyl-1-cyclohexanol Structure

1-Ethynyl-1-cyc...

~%

(2-cyclohexyl-2-ethoxyethenyl)sulfanylbenzene Structure

(2-cyclohexyl-2...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

(2-cyclohexyl-2-ethoxyethenyl)sulfanylbenzene Structure

(2-cyclohexyl-2...

Sodium ethoxide Structure

Sodium ethoxide

cyclohexylidene-oxo-phenyl-(2-phenylsulfanylethenyl)-λ6-sulfane Structure

cyclohexylidene...

~44%

(2-cyclohexyl-2-ethoxyethenyl)sulfanylbenzene Structure

(2-cyclohexyl-2...

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

~%

3-methyl-2-phenylsulfanylbut-2-enal Structure

3-methyl-2-phen...

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

~59%

(3-methyl-1-phenylsulfanylbut-2-enyl)sulfanylbenzene Structure

(3-methyl-1-phe...

3-Methyl butynol Structure

3-Methyl butynol

~%

(3-methyl-1-phenylsulfanylbut-2-enyl)sulfanylbenzene Structure

(3-methyl-1-phe...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

(3-methyl-1-phenylsulfanylbut-2-enyl)sulfanylbenzene Structure

(3-methyl-1-phe...

Sodium benzenethiolate Structure

Sodium benzenet...

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

~82%

2-methyl-3,4-bis(phenylsulfanyl)but-3-en-2-ol Structure

2-methyl-3,4-bi...

3-Methyl butynol Structure

3-Methyl butynol

~%

2-methyl-3,4-bis(phenylsulfanyl)but-3-en-2-ol Structure

2-methyl-3,4-bi...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

2-methyl-3,4-bis(phenylsulfanyl)but-3-en-2-ol Structure

2-methyl-3,4-bi...

Sodium benzenethiolate Structure

Sodium benzenet...

cyclohexylidene-oxo-phenyl-(2-phenylsulfanylethenyl)-λ6-sulfane Structure

cyclohexylidene...

~46%

1-[1,2-bis(phenylsulfanyl)ethenyl]cyclohexan-1-ol Structure

1-[1,2-bis(phen...

1-Ethynyl-1-cyclohexanol Structure

1-Ethynyl-1-cyc...

~%

1-[1,2-bis(phenylsulfanyl)ethenyl]cyclohexan-1-ol Structure

1-[1,2-bis(phen...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

1-[1,2-bis(phenylsulfanyl)ethenyl]cyclohexan-1-ol Structure

1-[1,2-bis(phen...

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

~56%

3-methylbuta-1,2-dienylsulfanylbenzene Structure

3-methylbuta-1,...

3-Methyl butynol Structure

3-Methyl butynol

~%

3-methylbuta-1,2-dienylsulfanylbenzene Structure

3-methylbuta-1,...

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

3-methylbuta-1,2-dienylsulfanylbenzene Structure

3-methylbuta-1,...

Propargyl alcohol Structure

Propargyl alcohol

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~%

3-phenylsulfanylprop-2-yn-1-ol Structure

3-phenylsulfany...

3-Methyl butynol Structure

3-Methyl butynol

(Chlorosulfanyl)benzene Structure

(Chlorosulfanyl...

~56%

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

(2-ethoxy-3-methylbut-1-enyl)sulfanylbenzene Structure

(2-ethoxy-3-met...

~53%

2-ethoxy-3-methylbut-2-enal Structure

2-ethoxy-3-meth...

3-Methyl butynol Structure

3-Methyl butynol

~%

2-ethoxy-3-methylbut-2-enal Structure

2-ethoxy-3-meth...

[1-(benzenesulfinyl)-3-methylbuta-1,2-dienyl]sulfanylbenzene Structure

[1-(benzenesulf...

~%

2-ethoxy-3-methylbut-2-enal Structure

2-ethoxy-3-meth...

o-Quinone Methides from 4-Allenylcyclobutenones: Synthesis a...

[Taing, Meng; Moore, Harold W. Journal of Organic Chemistry, 1996 , vol. 61, # 1 p. 329 - 340]

o-Quinone Methides from 4-Allenylcyclobutenones: Synthesis a...

[Taing, Meng; Moore, Harold W. Journal of Organic Chemistry, 1996 , vol. 61, # 1 p. 329 - 340]

o-Quinone Methides from 4-Allenylcyclobutenones: Synthesis a...

[Taing, Meng; Moore, Harold W. Journal of Organic Chemistry, 1996 , vol. 61, # 1 p. 329 - 340]