HAP-Pd (0): A Highly Efficient Recyclable Heterogeneous Catalyst for the Selective Reduction of Carbon–Carbon Double Bond in α, β-Unsaturated Ketones

OS Chambyal, S Paul, T Shamim, M Gupta…

Index: Chambyal, Omkar Singh; Paul, Satya; Shamim, Tahira; Gupta, Monika; Gupta, Rajive; Loupy, Andre Synthetic Communications, 2013 , vol. 43, # 5 p. 656 - 667

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Citation Number: 7

Abstract

A recyclable heterogeneous hydroxyapatite-supported palladium(0) catalyst was prepared by a simple procedure and successfully applied for the selective reduction of carbon–carbon double bond in α,β-unsaturated ketones using HCOONH 4 as hydrogen transfer agent. The workup procedure is simple, and the catalyst could be recovered by simple filtration and recycled for five consecutive runs without significant loss of activity. ... A recyclable heterogeneous ...