Tetrahedron Letters

Palladium-catalyzed carbonylative coupling reactions of aryl iodides with hexamethyldisilane (HMDS) to benzoyl silanes

XF Wu, H Neumann, M Beller

Index: Wu, Xiao-Feng; Neumann, Helfried; Beller, Matthias Tetrahedron Letters, 2012 , vol. 53, # 5 p. 582 - 584

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Citation Number: 11

Abstract

In the past two decades palladium-catalyzed carbonylations of aryl halides have become a powerful tool for the synthesis of all kinds of substituted (hetero) aromatic carboxylic acids and their derivatives. 6 More recently, aminocarbonylation of aryl halides with ammonia to primary amides, and carbonylative Sonogashira reactions of aryl bromides and aryl triflates to alkynones, and as well as carbonylative Heck reactions of aryl halides and aryl/vinyl ...