Ti/Ni??Based Multimetallic System for the Efficient Allylation of Carbonyl Compounds

…, AG Campaña, I Rodríguez??Márquez…

Index: Martinez-Peragon, Angela; Millan, Alba; Campana, Araceli G.; Rodriguez-Marquez, Irene; Resa, Sandra; Miguel, Delia; Alvarez De Cienfuegos, Luis; Cuerva, Juan M. European Journal of Organic Chemistry, 2012 , # 8 p. 1499 - 1503

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Citation Number: 6

Abstract

Abstract A mild method for the allylation of carbonyl compounds is presented. This methodology allows the allylation of a broad range of carbonyl compounds starting with allyl carbonates as pronucleophiles. Noteworthy is that ketones, infrequent substrates in other related protocols, are suitable substrates under these reaction conditions. Moreover, the reaction proceeds at room temperature with the use of catalytic amounts of both Ni and Ti ...