Pentafluoroselenium isocyanate and pentafluorotellurium isocyanate, Fe5SeN: C: O and Fe5TeN: C: O

P Huppmann, G Kloeter, JS Thrasher…

Index: Huppmann, Peter; Kloeter, Gerhard; Thrasher, Joseph S.; Seppelt, Konrad; DesMarteau, Darryl D. Inorganic Chemistry, 1984 , vol. 23, p. 2217 - 2219

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Citation Number: 11

Abstract

The previously unknown F5Se-N= C= O is prepared from Xe (OSeF5) 2 and HCN; F5Te-N= C= O can be prepared similarly but also by more straightforward routes. 2 Compared with that of F5S-N= C= O, the isocyanate reactivity is reduced in F, Te-N= C= O and even more so in F5Se-N= C= O.