A New Way to Access Chiral Liquid Crystals: Organocatalyst-Mediated Synthesis of Chiral Rod-Like Liquid Crystals

L Wang, XJ Liu, P Huang, QP Gong, YH Li…

Index: Wang, Li; Liu, Xiao-Jun; Huang, Ping; Gong, Qing-Ping; Li, Yong-Hong; Wang, Bi-Qin; Zhao, Ke-Qing Molecular Crystals and Liquid Crystals, 2011 , vol. 541, p. 53 - 59

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Abstract

In this article, an asymmetric organocatalytic way to prepare chiral liquid crystals from non- chiral starting materials was described. By using L-proline as the organocatalyst, several new chiral rod-like liquid crystals that are elusive with traditional methods were prepared. In addition, a series of novel enone-containing rod-like liquid crystals were also obtained as side-products. Mesomorphic properties of all new compounds were studied by Polarized ...