Tetrahedron

Reduction selective par le borohydrure de sodium d'un groupe ester ou nitrile dans les epoxydes gem disubstitues par deux croupes attracteurs d'electrons

J Mauger, A Robert

Index: Mauger, J.; Robert, A. Tetrahedron, 1988 , vol. 44, # 9 p. 2493 - 2502

Full Text: HTML

Citation Number: 10

Abstract

Sodium borohydride reduced the ester group of the epoxides 1 or one cyano group of 2 selectively within 5 minutes to give new hydroxy -or amino- functionalized epoxides. This unusual reduction of a cyano group has been extended to other α,α-dicyano derivatives. ... SE Ellzey Jr., JS Wittman Jr.III, WJ Connick Jr. ... Les spectres de RMN des mélanges réactionnels suggèrent la présence de traces des amino époxydes de structure cis. ... Cookies are used by this site. To ...

~92%

Solvent-free mechanochemical and one-pot reductive benzyliza...

[Zhang, Ze; Gao, Jie; Xia, Jing-Jing; Wang, Guan-Wu Organic and Biomolecular Chemistry, 2005 , vol. 3, # 9 p. 1617 - 1619]

Photosilylation of electron-deficient alkenes by use of disi...

[Mizuno, Kazuhiko; Nakanishi, Kazuhisa; Chosa, Jun-ichi; Nguyen, Tien; Otsuji, Yoshio Tetrahedron Letters, 1989 , vol. 30, # 28 p. 3689 - 3692]

Some 2, 4, 6-Triamino-5-alkyl-and 5-Benzylpyrimidines

[Russell; Hitchings Journal of the American Chemical Society, 1952 , vol. 74, p. 3443]

THE REACTIONS OF BENZYLIDENEMALONONITRILES AND β-NITROSTYREN...

[Itoh, Kazuyoshi; Ishida, Hideaki; Chikashita, Hidenori Chemistry Letters, 1982 , p. 1117 - 1118]

Some 2, 4, 6-Triamino-5-alkyl-and 5-Benzylpyrimidines

[Russell; Hitchings Journal of the American Chemical Society, 1952 , vol. 74, p. 3443]