Tetrahedron Letters

Photosilylation of electron-deficient alkenes by use of disilanes via photoinduced electron-transfer

K Mizuno, K Nakanishi, J Chosa, T Nguyen, Y Otsuji

Index: Mizuno, Kazuhiko; Nakanishi, Kazuhisa; Chosa, Jun-ichi; Nguyen, Tien; Otsuji, Yoshio Tetrahedron Letters, 1989 , vol. 30, # 28 p. 3689 - 3692

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Citation Number: 24

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The photosilylation on electron-deficient alkenes such as 1-aryl-2,2-dicyanoethenes occurred regioselectively at the β-position to the electron-withdrawing groups upon irradiation with disilanes and trisilane. ... Compound 3a: oil; 1 H NMR (270 MHz, CDCl 3 ) δ 0.14 (9H, s), 2.62 (1H, ...

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