Gas phase reaction of tetrachlorogermane with conjugated dienes in the presence of hexachlorodisilane initiator

…, GN Yakovleva, VG Bykovenko, VV Shcherbinin

Index: Chernyshev; Komalenkova; Yakovleva; Bykovenko; Shcherbinin; Belokon' Russian Journal of General Chemistry, 2001 , vol. 71, # 9 p. 1438 - 1442

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Citation Number: 3

Abstract

Abstract Studies of the reaction of GeCl 4 with acyclic conjugated dienes (1, 3-butadiene, 2- methyl-1, 3-butadiene, 2, 3-dimethyl-1, 3-butadiene) and cyclopentadiene in the presence of Si 2 Cl 6 initiator were carried out. With acyclic dienes, corresponding 1, 1-dichloro-1- germacyclo-3-pentenes and 1, 1-dichloro-1-silacyclo-3-pentenes are preferrably formed. With cyclopentadiene the main reaction products are cyclopentenyltrichlorogermanes and ...