Germanium chloride

Modify Date: 2024-01-03 10:27:57

Germanium chloride Structure
Germanium chloride structure
Common Name Germanium chloride
CAS Number 10038-98-9 Molecular Weight 214.45200
Density 1.844 Boiling Point 82-84ºC
Molecular Formula Cl4Ge Melting Point -49.5ºC
MSDS Chinese USA Flash Point 83.1°C
Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger

 Names

Name Germanium tetrachloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.844
Boiling Point 82-84ºC
Melting Point -49.5ºC
Molecular Formula Cl4Ge
Molecular Weight 214.45200
Flash Point 83.1°C
Exact Mass 213.79700
LogP 2.37720
Vapour Pressure 76 mm Hg ( 20 °C)
Index of Refraction 1.4644
Water Solubility DECOMPOSES

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LY5225000
CHEMICAL NAME :
Germanium chloride
CAS REGISTRY NUMBER :
10038-98-9
LAST UPDATED :
199701
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
Cl4-Ge
MOLECULAR WEIGHT :
214.39
WISWESSER LINE NOTATION :
.GE..G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(4),57,1964 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
44 gm/m3/2H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - conjunctive irritation Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(5),51,1968
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02625 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/m3/2H/40D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Blood - hemorrhage Related to Chronic Data - death
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(4),57,1964 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5834 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1717 (estimated) No. of Female Employees: 195 (estimated)

 Safety Information

Symbol GHS05 GHS06
GHS05, GHS06
Signal Word Danger
Hazard Statements H314-H330
Supplemental HS Reacts violently with water.
Precautionary Statements P260-P280-P284-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive;
Risk Phrases R14;R34
Safety Phrases S25-S36/37/39-S45-S8
RIDADR UN 3390
WGK Germany 3
RTECS LY5225000
Packaging Group II

 Synthetic Route

 Articles5

More Articles
Electrochemical vapor deposition of semiconductors from gas phase with a solid membrane cell.

J. Am. Chem. Soc. 137 , 6638-42, (2015)

We demonstrate the feasibility of semiconductor deposition via the electrochemical reduction of gaseous precursors by the use of an anhydrous proton-conducting membrane, the solid acid CsHSO4, at 165 ...

The Crystal Structure and Raman Spectrum of Ge(5)Cl(12).GeCl(4) and the Vibrational Spectrum of Ge(2)Cl(6).

Inorg. Chem. 37 , 6032, (1998)

The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is ver...

Catalytic conversion of carbohydrates into 5-hydroxymethylfurfural by germanium(IV) chloride in ionic liquids.

ChemSusChem 4(1) , 131-8, (2011)

Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly ...

 Synonyms

tetrachloro-german
Germanium(IV) Chloride (Metals Basis)
germanium(IV) chloride
tetrachloro-germaniu
GERMANIUM(+4)CHLORIDE
germanium(IV) tetrachloride
MFCD00011029
germaniumtetrachloride
EINECS 233-116-7
tetrachlorogermanium
germanium chloride
tetrachloro-Germane
GeCl4
Germane,tetrachloro
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