A general strategy for elaboration of the dithiocarbonyl functionality,-(C: O) SS-: application to the synthesis of bis (chlorocarbonyl) disulfane and related derivatives of …

…, AL Schroll, AW Mott, DA Halsrud

Index: Barany, George; Schroll, Alayne L.; Mott, Andrew W.; Halsrud, David A. Journal of Organic Chemistry, 1983 , vol. 48, # 24 p. 4750 - 4761

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Citation Number: 85

Abstract

A variety of sulfenyl chlorides have been reacted with a variety of alkoxythiocarbonyl compounds to give adducts which then lose (spontaneously, or upon thermolysis, or in the presence of a Lewis acid catalyst) the alkyl chloride to provide an assortment of dithiocarbonyl compounds in good to excellent yields. The preparations of bis- (chlorocarbony1) disulfane (I),((trichloromethy1) dithio) carbonyl chloride (2),(( ...